Chemical physics letters

An HTFFR kinetics study of the reaction between BCl and O2 from 540 to 1670 K

AG Slavejkov, DF Rogowski, A Fontijn

Index: Slavejkov, Aleksandar G.; Rogowski, Donald F.; Fontijn, Arthur Chemical Physics Letters, 1988 , vol. 143, p. 26 - 30

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Citation Number: 5

Abstract

Abstract A method for the production of BCl in flow systems has been developed and used for the study of the title reaction in a high-temperature fast-flow reactor (HTFFR). The temperature dependence of the rate coefficients is described by the expression k (T)= 2.2× 10− 11 exp (− 4620 K/T) cm 3 molecule− 1 s− 1, consistent with a single reaction mechanism for the given temperature range. These k (T) values are larger than those ...