Tetrahedron letters

Convenient preparation of optically pure propargylic alcohols using 2-(trimethylsilyl) vinyl sulfoxide as a novel chiral synthon

S Kusuda, K Kawamura, Y Ueno, T Toru

Index: Kusuda, Shinya; Kawamura, Kiyoshi; Ueno, Yoshio; Toru, Takeshi Tetrahedron Letters, 1993 , vol. 34, # 41 p. 6587 - 6590

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Citation Number: 10

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Both enantiomers of optically pure propargylic alcohols are conveniently prepared by the reaction of α-vinyl anion of 2-(trimethylsilyl)vinyl p-tolyl sulfoxide with aldehydes and subsequent either desilylsulfinylation or thermal elimination of the sulfinyl group. ... When the oxidation was ...

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