Tungsten and molybdenum 2-oxaallyl [. eta. 1-(C)-enolate] complexes: functional group transformations, photochemical aldol reactions, and alkyne/carbon monoxide …

ER Burkhardt, JJ Doney, RG Bergman…

Index: Burkhardt,E.R.; Doney,J.J.; Bergman,R.G. Journal of the American Chemical Society, 1987 , vol. 109, p. 2022

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Citation Number: 109

Abstract

Abstract: Carbon bound tungsten and molybdenum 2-oxaalkyl (7'-enolate) complexes 1-8 can be prepared easily by reaction of CSR5 (C0), M-Na'(R= H, CH3; M= W, Mo) with a- chloro esters, ketones, and amides. Secondary tungsten enolates 9 and 10 were ...

~20%

~47%

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