Molecules

Syntheses of (Diacetoxyiodo) arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant

P Kazmierczak, L Skulski, L Kraszkiewicz

Index: Kazmierczak, Pawel; Skulski, Lech; Kraszkiewicz, Lukasz Molecules, 2001 , vol. 6, # 11 p. 881 - 891

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Citation Number: 73

Abstract

Abstract:-Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)- arenes, ArI (OAc) 2, or iodylarenes, ArIO 2, from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2-and 4- iodylbenzoic acids, the respective sodium salts of 2-and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl ...