The Ultraviolet Absorption Spectra of Pyrimidines and Purines1

LF Cavalieri, A Bendich

Index: Cavalieri; Bendich Journal of the American Chemical Society, 1950 , vol. 72, p. 2587,2593

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Citation Number: 126

Abstract

Results 2, 6-and 4, 6-disubstituted and 2, 4, 6-trisubstituted pyrimidines exhibit a maximum in the region of 264* 6 mp (Fig. 1); the 2, 4, 6-tri-substituted-5formamidopyrimidines possess a band at 265* 6 rnp. In a homogeneous series, the molecular extinction coefficients decrease in the order: 2, 4, 6-trisubstituted> 2, 4, 6-trisubstituted-5-formamido> 4, 6- disubstituted> 2, 6-disubstituted. In both the 2, 6-and 4, 6-disubstituted pyrimidines an ...