Generation and Reaction of (N-Aryltrifluoroacetimidoyl) zinc Halide.

K Tamura, F Yan, T Sakai, K Uneyama

Index: Tamura, Kenji; Yan, Fengyang; Sakai, Takashi; Uneyama, Kenji Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 1 p. 300 - 303

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Citation Number: 17

Abstract

(N-Aryltrifluoroacetimidoyl) zinc halides were easily generated at room temperature by the oxidative addition of imidoyl halides to activated zinc powder.[N-(2, 6-Dichlorophenyl)-and N- (2, 6-dimethylphenyl) trifluoroacetimidoyl] zinc halides react with aldehydes to give the corresponding alcohols smoothly in good to excellent yields. These adducts could be readily transformed to the α-amino ketones.

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