Mixed ligation to vanadium (III): Synthesis, spectra and structures of bis (acetylacetonato)(o-phenanthroline) vanadium (III) fluoroborate and bis (acetylacetonato)(o- …

SJ Kavitha, K Panchanatheswaran, MRJ Elsegood…

Index: Kavitha, Savaridasson Jose; Panchanatheswaran, Krishnaswamy; Elsegood, Mark R.J.; Dale, Sophie H. Inorganica Chimica Acta, 2006 , vol. 359, # 4 p. 1314 - 1320

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Citation Number: 10

Abstract

Two mixed ligand vanadium (III) complexes bis (acetylacetonato)(phenanthroline) vanadium (III) fluoroborate (1) and bis (acetylacetonato)(phenanthroline) vanadium (III) perchorate (2) have been prepared and characterized by UV–Vis, IR, 1H NMR spectroscopic techniques and single crystal X-ray diffraction. The electronic spectra are as expected for V (III) in an octahedral environment. The 1H NMR spectra are typical of paramagnetic V (III) species. ...