Inorganic Chemistry

Molecular vapor synthesis: the use of titanium monoxide and vanadium monoxide vapors as reagents

TJ Groshens, KJ Klabunde

Index: Groshens, Thomas J.; Klabunde, Kenneth J. Inorganic Chemistry, 1990 , vol. 29, p. 2979 - 2982

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Abstract

The production and reactivity of titanium monoxide (TiO) and vanadium monoxide (VO) on a synthetically useful scale were studied by using the techniques and apparatus previously developed for reactions of metal atoms. Cocondensation reactions with chlorine showed that greater amounts of metal atoms were produced as impurities in the vapor when stoichiometric metal monoxides were used as vapor sources than when metal ...