Journal of the American Chemical Society

THE SPONTANEOUS DISSOCIATION OF TRIPHENYLMETHYL DISULFIDE WITH THE FORMATION OF TRIPHENYL-METHYL. THE POTASSIUM DERIVATIVE OF …

FF Blicke

Index: Blicke Journal of the American Chemical Society, 1923 , vol. 45, p. 1969

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Citation Number: 7

Abstract

N-Pentamethylene-S-triarylmethyl-dithio-urethans dissociate spontaneously, in solution, with the formation of triarylmethyls; the latter were isolated in the form of their characteristic peroxides1 It has now been found that triphenylmethyl disulfide also dissociates spontaneously, in solution, at ordinary temperature with the formation of triphenylmethyl; thus, when the colorless disulfide is dissolved in benzene the solution, colorless at first, ...