Journal of the American Chemical Society

Stereochemistry and mechanisms of reactions of dioxygen complexes with organic electrophiles as studied by use of chiral reagents and isotopic labeling

Y Tatsuno, S Otsuka

Index: Tatsuno, Y.; Otsuka, Sei Journal of the American Chemical Society, 1981 , vol. 103, # 19 p. 5832 - 5839

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Citation Number: 39

Abstract

Abstract: From reactions of PtOIL,(L= PPh3, P (c-C6H1J3) with 1 mol of triphenylmethyl bromide or benzoyl bromide the corresponding (alkylperoxo) platinum (II) complexes L2PtBr (OOR)(la, L= PPh3, R= CPh,; lb, L= P (c-C6H1J3, R= CPh,; 2, L= PPh3, R= COPh) were isolated, which were well characterized by elemental analysis and IR spectroscopy. The complex la, b or 2 was treated with another mole of organic halides to give the ...