Tetrahedron letters

New allyl group acceptors for palladium catalyzed removal of allylic protections and transacylation of allyl carbamates

M Dessolin, MG Guillerez, N Thieriet, F Guibé, A Loffet

Index: Dessolin, Michele; Guillerez, Marie-George; Thieriet, Nathalie; Guibe, Francois; Loffet, Albert Tetrahedron Letters, 1995 , vol. 36, # 32 p. 5741 - 5744

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Citation Number: 141

Abstract

Allyl carboxylates, carbamates and phenoxides may be cleaved or transacylated in the presence of palladium catalyst and either phenyltrihydrosilane or N-methyl-N-(trimethylsilyl)- trifluoroacetamide. These reactions are totally compatible with the presence of Boc and, as far as phenyltrihydrosilane is concerned, Fmoc protections.

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