Since Migita1 succeeded in synthesizing disubstituted aniline derivatives from arylpalladium complex and dialkylstannane, a method for synthesizing mono-and disubstituted aniline derivatives from aryl halides using palladium catalyst has been established by the ingenious studies of Buchwald and Hartwig. 2 However, synthesis of nonsubstituted aniline derivatives from arylpalladium complex was not known because we must use NH3 for that purpose. ...
[Hoi, Ka Hou; Calimsiz, Selcuk; Froese, Robert D. J.; Hopkinson, Alan C.; Organ, Michael G. Chemistry - A European Journal, 2012 , vol. 18, # 1 p. 145 - 151]
