Rates and products of acetolysis of p-nitroneophyl p-bromobenzesulfonate

H Tanida, T Tsuji, H Ishitobi, T Irie

Index: Tanida,H. et al. Journal of Organic Chemistry, 1969 , vol. 34, p. 1086 - 1089

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Citation Number: 10

Abstract

pNitrc-and pcyanoneophyl brosylates were synthesized and their acetolysis rates were determined. The acetolysis of the nitro brosylate proceeds with 72.2% phenyl rearrangement and 25.47, methyl rearrangement forming four kinds of olefins@, p-dimethyl-pnitrostyrene, a, p-dimethyl-pnitrostyrene, a-ethyl-pnitrostyrene, and% methyl-3-(pnitrophenyl) prop-l-ene) and three kinds of acetates (p-nitroneophyl acetate, dimethylpnitrobensylcarbinyl acetate, ...