e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Identification and formation pathway of laccase-mediated oxidation products formed from hydroxyphenylureas

…, L Neuville, FD Boyer, L Kerhoas…

Index: Jolivalt; Neuville; Boyer; Kerhoas; Mougin Journal of Agricultural and Food Chemistry, 2006 , vol. 54, # 14 p. 5046 - 5054

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Citation Number: 18

Abstract

Hydroxyphenylureas are the first main metabolites formed in the environment from pesticide and biocide urea compounds. Because fungi release potent exocellular oxidases, we studied the ability of laccases produced by the white rot fungus, T. versicolor, to catalyze in vitro the transformation of five hydroxyphenylureas, to identify transformation pathways and mechanisms. Our results establish that the pH of the reaction has a strong influence on ...

4-chloro-2-hydroxybenzoyl azide Structure

4-chloro-2-hydr...

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

N/A Structure

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

Benzoic acid,4-chloro-2-hydroxy-, methyl ester Structure

Benzoic acid,4-...

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

4-Chloro-2-hydroxybenzohydrazide Structure

4-Chloro-2-hydr...

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

N/A Structure

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

N/A Structure

~%

3-(4-chloro-2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-chloro-2-h...

Benzoic acid,4-chloro-2-hydroxy-, methyl ester Structure

Benzoic acid,4-...

~%

4-Chloro-2-hydroxybenzohydrazide Structure

4-Chloro-2-hydr...

2-Benzoxazolinone Structure

2-Benzoxazolinone

Dimethylamine Structure

~30%

3-(2-hydroxyphenyl)-1,1-dimethylurea Structure

3-(2-hydroxyphe...

N/A Structure

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

N/A Structure

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

Methyl 3-chloro-4-hydroxybenzoate Structure

Methyl 3-chloro...

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

3-chloro-4-hydroxybenzoic acid hydrazide Structure

3-chloro-4-hydr...

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

N/A Structure

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

2-chloro-4-isocyanatophenyl acetate Structure

2-chloro-4-isoc...

~%

1-(3-Chloro-4-hydroxyphenyl)-3,3-dimethylurea Structure

1-(3-Chloro-4-h...

N/A Structure

~%

3-(4-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-hydroxyphe...

4-Hydroxybenzhydrazide Structure

4-Hydroxybenzhy...

~%

3-(4-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-hydroxyphe...

Methyl 4-hydroxybenzoate Structure

Methyl 4-hydrox...

~%

3-(4-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-hydroxyphe...

4-(3,3-dimethylureido)phenyl acetate Structure

4-(3,3-dimethyl...

~%

3-(4-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-hydroxyphe...

4-acetoxyphenyl isocianate Structure

4-acetoxyphenyl...

~%

3-(4-hydroxyphenyl)-1,1-dimethylurea Structure

3-(4-hydroxyphe...