Organic & biomolecular chemistry

Polymer supported naphthalene-catalysed sodium reactions

TR van den Ancker, CJ Love

Index: Van Den Ancker, Tania R.; Love, Cameron J. Organic and Biomolecular Chemistry, 2007 , vol. 5, # 21 p. 3520 - 3523

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Citation Number: 3

Abstract

Arene-catalysed sodium reactions have been utilised in the generation of organosodium complexes, from a variety of organochloride complexes, in high yield. Phenyltrimethylsilane, benzene and 2-methyl-1-phenyl-1-propanol were prepared in yields> 80%, using polymer supported naphthalene-catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and polymer-supported naphthalene (5– ...