… of palladium (II) with 1, 4-benzodiazepin-2-ones. Crystal structure of (LH) Pd (PPh 3) Cl· CHCl 3 (L= Prazepam: 7-chloro-1-cyclopropylmethyl-1, 3-dihydro-5-phenyl- …

…, S Gladiali, G Minghetti, S Stoccoro, F Demartin

Index: Cinellu, Maria Agostina; Gladiali, Serafino; Minghetti, Giovanni; Stoccoro, Sergio; Demartin, Francesco Journal of Organometallic Chemistry, 1991 , vol. 401, # 3 p. 371 - 384

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Citation Number: 19

Abstract

Abstract The dimeric cyclometallated derivatives of palladium (II)[(LH) PdCl] 2, 3 (L= 1, Diazepam: 7-chloro-1, 3-dihydro-1-methyl-5-phenyl-2H-1, 4-benzodiazepin-2-one) and 4 (L= 2, Prazepam: 7-chloro-1-cyclopropylmethyl-1, 3-dihydro-5-phenyl-2H-1, 4- benzodiazepin-2-one) react with triphenylphosphine to give the complexes (LH) Pd (PPh 3) Cl, 5 (L= Diazepam) and 6 (L= Prazepam). The crystal structure of 6 was determined by X- ...