Synthesis of pyrido [1, 2-a]-1, 3, 5-triazines. Reactions of 2-pyridyl isothiocyanate with compounds containing a C= N bond

M Marchalín, J Světlík, A Martvoň

Index: Marchalin, Miroslav; Svetlik, Jan; Martvon, Augustin Collection of Czechoslovak Chemical Communications, 1981 , vol. 46, # 10 p. 2557 - 2563

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Citation Number: 4

Abstract

Abstract New pyrido [1, 2-a]-1, 3, 5-triazine derivatives were prepared by the [4+ 2] cycloaddition reaction of 2-pyridyl isothiocyanates with isocyanate, aldimines, and N, N'- diphenylcarbodiimide. On the other hand, reaction of 2-pyridyl isothiocyanate with aliphatic carbodiimides afforded [2+ 2] cycloaddition products, 1, 3-thiazetidines.