Podands Based on 1, 4, 5, 8??Tetra??Azaphenanthrene and Their Complexation With Ru2+

…, SH Chao, R Nasielski??Hinkens

Index: Nasielski, J.; Chao, S. -H.; Nasielski-Hinkens, R. Bulletin des Societes Chimiques Belges, 1989 , vol. 98, # 6 p. 375 - 386

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Citation Number: 5

Abstract

Summary. New podands, based on 1, 4, 5, 8-tetra-azaphenanthrene, have been synthesized from 2-chloro-1, 4, 5, 8-tetra-azaphenanthrene 3; when the anchoring group is a nitrogen atom, the corresponding podands are, however, unstable. When reacted with Ru 2+ in an ionizing solvent, podands tris (2-(2-(1, 4, 5, 8-tetra-azaphenanthryloxy)) ethyl) methane 4c and tri (2-(2-(1, 4, 5, 8-tetra-azaphenanthryloxy)) ethyl) trimesoate 9 give only ...