Tetrahedron letters

Radical isomerization via intramolecular ipso substitution of aryl ethers: Aryl translocation from oxygen to carbon

L Eun, L Chulbom, ST Jin, SW Ho, SL Kap

Index: Lee, Eun; Lee, Chulbom; Tae, Jin Sung; Whang, Ho Sung; Li, Kap Sok Tetrahedron Letters, 1993 , vol. 34, # 14 p. 2343 - 2346

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Abstract

Abstract Bromopropyl aryl ethers an converted to 3-arylpropanols under standard radical generating conditions in the presence of tributylstannane and AIBN. This rearrangement involves intramolecular ipso attack of the alkyl radicals which generates spiro