Polycations-12. The synthesis of liquid ionic phosphates (LIPs) from mono-and polycationic ammonium halides

…, R Casiano, M Thomas, A Rikin, J Gaillard, R Raju…

Index: Lall, Sharon; Behaj, Valbona; Mancheno, Danny; Casiano, Robert; Thomas, Marie; Rikin, Amir; Gaillard, Jennifer; Raju, Ravinder; Scumpia, Alexander; Castro, Steve; Engel, Robert; Cohen, JaimeLee Iolani Synthesis, 2002 , # 11 p. 1530 - 1540

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Citation Number: 24

Abstract

Abstract Preparations are reported for an extensive series of phosphate salts of polyammonium species from the corresponding halide salts. The phosphate salts, as anhydrous materials, are liquid at or near room temperature. Three approaches for the preparation of these materials are noted, including treatment with aqueous hexafluorophosphoric acid, classical ion exchange methods, and treatment with 85% ...