Journal of fluorine chemistry

Electrochemical fluorination of di-and tri-(2-hydroxyethyl)-substituted alkylamines

T Abe, I Soloshonok, H Baba, A Sekiya

Index: Abe, Takashi; Soloshonok, Irina; Baba, Hajime; Sekiya, Akira Journal of Fluorine Chemistry, 1999 , vol. 99, # 1 p. 51 - 57

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Citation Number: 6

Abstract

Several 2-(hydroxyethyl)-substituted alkylamines like 1, 4-bis (2-hydroxyethyl) piperazine, N, N-bis (2-hydroxyethyl) methylamine, N, N-bis (2-hydroxyethyl) ethylamine, and N, N, N-tris (2- hydroxyethyl) amine as well as their derivatives (HCl salts, a borate and trimethylsilylethers) were subjected to electrochemical fluorination. From 1, 4-bis (2-hydroxyethyl) piperazine, F- [1, 4-bis (fluorocarbonylmethyl) piperazine] was obtained in low yield. In the fluorination of ...