The electrochemical fluorination of nitrogen-containing carboxylic acids. Fluorination of methyl esters of 3-dialkylamino propionic acids

…, E Hayashi, H Fukaya, Y Hayakawa, H Baba…

Index: Abe, Takashi; Hayashi, Eiji; Fukaya, Haruhiko; Hayakawa, Yoshio; Baba, Hajime; et al. Journal of Fluorine Chemistry, 1992 , vol. 57, p. 101 - 111

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Citation Number: 26

Abstract

Abstract Six methyl esters of 3-dialkylamino-substituted propionic acids were subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides. The following dialkylamino substituents were investigated: diethylamino, di-n-propyl-amino, di-n- butylamino, pyrrolidino, morpholino and piperidino groups. These perfluoroacid fluorides, which were obtained in fair yields, are considered to be prospective key precursors for ...