Relevance of conformational constraints to the regioselective lithiation of aromatic diethers. Application to the convenient construction of the DEF tricyclic subunit of the …

LA Paquette, MM Schulze, DG Bolin

Index: Paquette, Leo A.; Schulze, Matthias M.; Bolin, David G. Journal of Organic Chemistry, 1994 , vol. 59, # 8 p. 2043 - 2051

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Citation Number: 28

Abstract

Relevance of Conformational Constraints to the Regioselective Lithiation of Aromatic Diethers. Application to the Convenient Construction of the DEF Tricyclic Subunit of the Austalides ... Leo A. Paquette; Matthias M. Schulze,la and David G. BolinIb Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210 ... The lithiation of 29 and 30 is shown to occur at all three sites with a dissimilar kinetic preference. For the ...