Tetrahedron Letters

Primary amines via electrophilic amination of organometallic compounds with o-(diphenylphosphinyl) hydroxylamine

G Boche, M Bernheim, W Schrott

Index: Boche, Gernot; Bernheim, Michael; Schrott, Wolfgang Tetrahedron Letters, 1982 , vol. 23, # 51 p. 5399 - 5402

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Citation Number: 50

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... It is shown that O-(diphenylphosphinyl)hydroxylamine transforms all kinds of “carbanions” into primary amines; best yields are received with “stabilized anions”, eg of the benzylic type. ... The preparation of primary amines from “carbanions” and azides as electrophilic amination ...