Journal of organometallic chemistry

Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis

A Kunai, J Ohshita

Index: Kunai, Atsutaka; Ohshita, Joji Journal of Organometallic Chemistry, 2003 , vol. 686, # 1-2 p. 3 - 15

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Citation Number: 27

Abstract

Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X= Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu (II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo-and bromosilanes ...