Tetrahedron letters

Phospha-adamantanes as ligands for organopalladium chemistry: aminations of aryl halides

D Gerristma, T Brenstrum, J McNulty, A Capretta

Index: Gerristma, David; Brenstrum, Timothy; McNulty, James; Capretta, Alfredo Tetrahedron Letters, 2004 , vol. 45, # 45 p. 8319 - 8321

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Citation Number: 29

Abstract

The palladium-catalyzed amination of aryl or heteroaryl halides represents one of the most versatile methods for the preparation of functionalized anilines. 1 In recent years, the scope of this reaction has been enhanced as a result of the utilization of new phosphine ligands that permit these aminations to take place under milder conditions and with reaction partners that did not previously participate in coupling. 2 Indeed, many other organopalladium coupling reactions have benefited ...