Tetrahedron letters

Synthesis and Diels-Alder reactivity of simple 1-phenoxy-1, 3-dienes

…, F Guilhot, JL López, M Medarde, H Sahagún, F Tomé

Index: Caballero, Esther; Guilhot, Fabien; Lopez, Jose Luis; Medarde, Manuel; Sahagun, Heidi; Tome, Fernando Tetrahedron Letters, 1996 , vol. 37, # 38 p. 6951 - 6954

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Citation Number: 13

Abstract

An easy and useful method for the preparation of simple 1-phenoxy-2-trialkylsiloxy-1, 3- dienes in high yields, has been established and their reactivity in the Diels-Alder reaction at room temperature has been studied. By this procedure, phenoxy substituted cyclohexenes and cyclohexanones of known relative stereochemistry can be obtained.