The Oxidation of N??Benzylaziridine Catalyzed by Iron Porphyrin: Radical versus Electron Transfer Mechanism

…, C Dagostin, C Florea, C Galli, P Gentili…

Index: Cuppoletti, Andrea; Dagostin, Claudio; Florea, Cristina; Galli, Carlo; Gentili, Patrizia; Lanzalunga, Osvaldo; Petride, Aurica; Petride, Horia Chemistry - A European Journal, 1999 , vol. 5, # 10 p. 2993 - 2999

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Citation Number: 17

Abstract

Abstract Use of an amine endowed with a high oxidation potential induces a shift in mechanism from the electron transfer to the hydrogen-atom transfer (HAT) route in the biomimetic oxidative N-Dealkylation reaction, as shown by an investigation of the pattern of products from the reaction of N-benzylaziridine (see scheme).

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