e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis (isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid- …
EG Janzen, PH Krygsman, DA Lindsay…
Index: Janzen, Edward G.; Krygsman, Peter H.; Lindsay, David A.; Haire, D. Larry Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8279 - 8284
Abstract The thermolysis of azobis (isobutyronitri1e)(AIBN) in the presence of oxygen has been investigated by spin trapping by using@-phenyl N-terf-butyl nitrone (PBN) and 5, s- dimethylpyrroline N-oxide (DMPO). The aminoxyl products identified by ESR and mass spectroscopy (MS) are the result of trapping 2-cyano-2-propyl radicals (CP) in the presence of oxygen. By low-temperature ESR the 2-cyano-2-propylperoxyl adduct of PBN-ni~ onyl-l ...
