Organometallics

Fe-Catalyzed Nucleophilic Activation of C–Si versus Allylic C–O Bonds: Catalytic Trifluoromethylation of Carbonyl Groups versus Tandem Trifluormethylation– …

JEMN Klein, S Rommel, B Plietker

Index: Trivedi, Rushi; Tunge, Jon A. Organic Letters, 2009 , vol. 11, # 24 p. 5650 - 5652

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Citation Number: 6

Abstract

... Volume: Page: ... of an organic substrate (eg, an allyl carbonate) occurs via electron transfer from one of the two Fe–N π bonds into a π* orbital at the unsaturated organic substrate, resulting ... Furthermore, aryl bromides were tolerated, giving rise to 10 and 11. ...