Inorganic Chemistry

Synthesis and crystal structure of [(Ph3P) 2 (CO) 2 (S2N2) RuCl]+ AlCl4-. Preparation of novel S2N2 complexes

HW Roesky, J Anhaus, WS Sheldrick

Index: Roesky, H. W.; Anhaus, J.; Sheldrick, W. S. Inorganic Chemistry, 1984 , vol. 23, p. 75 - 79

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Citation Number: 29

Abstract

The complex [(Ph3P) 2 (CO) 2 (S2N2) Ru~ l]+ AlC&-has been prepared by the reaction of (Ph3P) 2 (C0) 2RuC12 with S2N2. 2A1C13, and its structure is determined by single-crystal X-ray analysis. It crystallizes in the monoclinic space group Cc with a= 10.365 (1) A, b= 23.185 (5) A, c= 18.361 (3) A, fl= 106.06 (1) O, and Z= 4. The structure was refined to R= 0.041, R,= 0.038 for 3292 reflections with I 1 2.0 (a (Z)). In the cation the S2N2 is ...