Vaporization of (SN) x. He I photoelectron spectrum and ab initio calculations for the S3N3 radical

…, NPC Westwood, MH Palmer

Index: Lau, W. M.; Westwood, N. P. C.; Palmer, M. H. Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3229 - 3237

Full Text: HTML

Citation Number: 26

Abstract

Summary Differences in rates of benzyl C-CH3 homolysis for reactions 2-6 and 7-9 were used to derive differences in resonance stabilities (RSE) of the benzylic radical products of these reactions. Structure Resonance Theory gave values of RSE in good agreement with our experimental results; however, a significant difference is found between our experimental RSE for DPhMe. and that reported in the literature for the related 10-hydro-9- ...