Organic & biomolecular chemistry

… turnover catalyst for the decomposition of P [double bond, length as m-dash] S insecticides. Mechanistic studies of the methanolysis of some P [double bond, length …

ZL Lu, AA Neverov, RS Brown

Index: Lu, Zhong-Lin; Neverov, Alexei A.; Brown, R. Stan Organic and Biomolecular Chemistry, 2005 , vol. 3, # 18 p. 3379 - 3387

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Citation Number: 44

Abstract

An ortho-palladated complex Pd (dmba)(py)(OTf)(9), or Pd (N, N-dimethylbenzylamine)( pyridine)(trifluoromethanesulfonate), was synthesized and its solution properties in methanol studied as a function of sspH. In neutral solution the triflate dissociates from the complex to give a dominant form Pd (dmba)(py)(HOCH3), and in acid the pyridine dissociates to give Pyr–H+ and Pd (dmba)(HOCH3)(HOCH3). Under basic conditions, Pd ...