Derivatives of 4-chloro-3, 5-dinitrobenzotrifluoride. 3. Synthesis of 1, 6-dinitro-3, 8-bis (trifluoromethyl) thianthrene and related compounds

JJ D'amico, CC Tung, WE Dahl…

Index: D'Amico,J.J. et al. Journal of Organic Chemistry, 1977 , vol. 42, p. 2896 - 2899

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Citation Number: 11

Abstract

NO, structure A taken. As noted in Figure 1, this study furnished definitive proof that the compound isolated in reaction 3 possessed structure 1. The molecule 1 has two planar halves which form an angle of 137". Each sulfur atom is in the plane of one benzene ring, tQ which it is slightly more closely bonded, and 0.13 (1) A out of the planes of the rings to which they are attached by 32 (1)". The S1 to 03 distance of 2.727 (9) A is the same as the S2 to ...