Synthesis, crystal structure and biological evaluation of a main group seven-coordinated bismuth (III) complex with 2-acetylpyridine N 4-phenylthiosemicarbazone

YK Li, M Yang, MX Li, H Yu, HC Wu, SQ Xie

Index: Li, Yan-Ke; Yang, Min; Li, Ming-Xue; Yu, Han; Wu, He-Chen; Xie, Song-Qiang Bioorganic and Medicinal Chemistry Letters, 2013 , vol. 23, # 8 p. 2288 - 2292

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Citation Number: 5

Abstract

Up to now, bismuth (III) complexes with thiosemicarbazones have been comparatively rare. Here, a main group seven-coordinated bismuth (III) complex [Bi (L)(NO3) 2 (CH3CH2OH)](1)(HL= 2-acetylpyridine N (4)-phenylthiosemicarbazone) has been synthesized and characterized by elemental analysis, IR, 1H NMR and single-crystal X-ray diffraction studies. The cytotoxicity data suggest that 1 exhibits higher in vitro ...