Journal of organometallic chemistry

Studies in aryltin chemistry. X. Synthesis and NMR spectra (119 Sn and 13 C) of some meta-and ortho-substituted tetra-and triaryltin compounds. The crystal and …

I Wharf, MG Simard

Index: Wharf, Ivor; Simard, Michel G. Journal of Organometallic Chemistry, 1997 , vol. 532, # 1-2 p. 1 - 9

Full Text: HTML

Citation Number: 29

Abstract

Several new tetra-aryltin compounds, Ar4Sn (Ar= 3, 5-(CH3) 2C6H3, 3, 5-Z2C6H3, and m- ZC6H4 (Z= F, Cl] and Ar3SnX [X= Cl, Br, I: Ar= 3, 5-(CH3) 2C6H3, m-and o-CH3OC6H4; X= Br; Ar= m-ZC6H4 (Z= F, Cl)] have been synthesized by literature methods and complete solution NMR data (119Sn, 13C) are reported for these and other meta-and ortho- substituted aryltins. Meta-substituents appear to exert electronic effects on chemical shifts ...