Journal of the American Chemical Society

Organic sulfur chemistry. 42. Sulfur-sulfur bond cleavage processes. Selective desulfurization of trisulfides

DN Harpp, RA Smith

Index: Harpp, David N.; Smith, Roger A. Journal of the American Chemical Society, 1982 , vol. 104, # 22 p. 6045 - 6053

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Citation Number: 70

Abstract

Abstract: The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail. A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.

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3,4-toluenedithiol Structure

14173-25-2

3,4-toluenedithiol

N/A Structure

16601-19-7

N/A

~%

Phenyl Phenylmethyl Disulfide Structure

16601-17-5

Phenyl Phenylme...

1-methyl-4-(methyldisulfanyl)benzene Structure

57266-34-9

1-methyl-4-(met...

benzyl trisulfide Structure

6493-73-8

benzyl trisulfide

~%

(butyldisulfanyl)methylbenzene Structure

16601-16-4

(butyldisulfany...

N/A Structure

4991-51-9

N/A

~%

(butyldisulfanyl)methylbenzene Structure

16601-16-4

(butyldisulfany...

benzyl trisulfide Structure

6493-73-8

benzyl trisulfide

~0%

Dibenzyl disulfide Structure

150-60-7

Dibenzyl disulfide

1,4-dibenzyltetrasulfane Structure

4816-54-0

1,4-dibenzyltet...

3,4-toluenedithiol Structure

14173-25-2

3,4-toluenedithiol

~%

1-methyl-4-(phenyldisulfanyl)benzene Structure

29627-34-7

1-methyl-4-(phe...

para-Tolyl disulfide Structure

103-19-5

para-Tolyl disulfide

Diphenyl disulfide Structure

882-33-7

Diphenyl disulfide

~%

1-methyl-4-(phenyldisulfanyl)benzene Structure

29627-34-7

1-methyl-4-(phe...


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