Reactions of Dialkoxyalkanes with Alkynylmagnesium Bromides1

AL Kranzfelder, RR Vogt

Index: Kranzfelder; Vogt Journal of the American Chemical Society, 1938 , vol. 60, p. 1715

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Citation Number: 26

Abstract

It has been shown by Spaeth2 and by Tschitschibabin and Jelgasin3 that several common acetals react with certain alkyl-and arylmagnesium halides to yield various amounts of ethers through replacement of one alkoxyl group by the hydrocarbon radical. This reaction has been applied in the present research by utilizing the acetylenic magnesium bromides and acetal-type compounds for the synthesis of alkyl ethers of alkynyl carbinols and ...