Journal of Organometallic Chemistry

New reactions and reagents.: VIII. A novel general synthesis of dialkylboranes and their derivatives via the transformations of dialkyl (diethylamino) boranes

SK Gupta

Index: Gupta,S.K. Journal of Organometallic Chemistry, 1978 , vol. 156, p. 95 - 99

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Abstract

Abstract This communication describes three developments which permit convenient synthesis of dialkylboranes, dialkylborinic acids and esters, and mixed trialkylboranes from readily synthesized dialkyl (diethylamino) boranes. These reactions proceed cleanly and quantitatively. The isolation or purification of the intermediates is not necessary. These developments are:(i) the reduction of o-hydroxyphenyldialkylborinates with aluminum ...