Journal of the American Chemical Society

SOME REACTIONS OF SUBSTITUTED MERCAPTOMAGNESIUM HALIDES

H Gilman, WB King

Index: Gilman; King Journal of the American Chemical Society, 1925 , vol. 47, p. 1141

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Citation Number: 6

Abstract

The reaction between organomagnesium halides and organic sulfur compounds is generally associated with the intermediate formation of the mercaptomagnesium halide group (-SMgX). In connection with studies concerned with the mechanism of reaction and the proof of structure, it was necessary to find some reliable reagent that will replace the- MgX group attached to sulfur by another in order to get a compound that lends itself to ...