Synthesis

Palladium-catalyzed R (sp3)-Zn/R (sp)-SnBu3 oxidative cross-coupling

L Jin, Y Zhao, H Wang, A Lei

Index: Jin, Liqun; Zhao, Yingsheng; Wang, Haibo; Lei, Aiwen Synthesis, 2008 , # 4 p. 649 - 654

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Citation Number: 15

Abstract

Abstract A novel bond formation through oxidative cross-coupling with desyl chloride as the oxidant has been investigated. The coupling can be carried out under mild conditions. The Csp 3-center carbon was involved even in the presence of a β-H, and up to 90% of the ...