Alkaline hydrolysis of N-ethyl-2, 4-dinitroacetanilide

J Skarzewski, M Aoki, S Sekiguchi

Index: Skarzewski, Jacek; Aoki, Masaru; Sekiguchi, Shizen Journal of Organic Chemistry, 1982 , vol. 47, # 9 p. 1764 - 1766

Full Text: HTML

Citation Number: 8

Abstract

Results Kinetic Runs. The hydrolysis of 2 with a large excess of hydroxide ion was followed spectrophotometrically in water containing 0.05%(v/v) of acetonitrile (b= 0.8 M, NaCl), and the reaction showed very good pseudo-firstorder kinetics. Table I shows the sodium hydroxide concentration dependence of k,(pseudo-first-order constant). At every temperature studied the pseudo-first-order rate constant (k,) showed a nonlinear ...