Nucleophilic and acid catalyst behavior of a protic ionic liquid in a molecular reaction media. Part 1

…, GG Fortunato, PM Mancini

Index: Adam, Claudia G.; Fortunato, Graciela G.; Mancini, Pedro M. Journal of Physical Organic Chemistry, 2009 , vol. 22, # 5 p. 460 - 465

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Citation Number: 13

Abstract

Abstract This work presents a new approach using ionic liquids, namely ethylammonium nitrate. The aim was to analyze how the addition of small amounts of a protic ionic liquid to a pure molecular solvent, modifies the microscopic characteristics of a reaction medium. In order to achieve this, a kinetic study of nucleophilic aromatic substitution reactions between 1-fluoro-2, 4-dinitrobenzene and 1-butylamine or piperidine was developed in this type of ...