Reactions of nitrosophenols. VI. Preparation of some hydroxyphenoxazones

E Ružička, V Bekárek, P Heinz

Index: Ruzicka,E. et al. Collection of Czechoslovak Chemical Communications, 1972 , vol. 37, p. 1905 - 1907

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Citation Number: 1

Abstract

The preparation of 2, 4-dimethyl-7, 9-dihydroxy-3-phenoxazone, 2, 4-dimethyJ-7-hydroxy-3- phenoxazone-9-carboxylic acid, and 9-hydroxy-5-benzo [a] phenoxazone-11-carboxylic acid by the reaction of corresponding nitrosophenols with phloroglucinol or 3, 5- dihydroxybenzoic acid in ethylene glycol solutions is described. The tautomerism in the prepared compounds is discussed on the basis of their acetylation and IR and PMR ...