Langmuir

Determination of an ion exchange constant by the use of a kinetic probe: a new semiempirical kinetic approach involving the effects of 3-F-and 4-F-substituted …

NSM Yusof, MN Khan

Index: Khan, Mohammed Niyaz Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988 , p. 213 - 220

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Citation Number: 13

Abstract

Pseudo-first-order rate constants (k obs) for the nucleophilic substitution reaction of piperidine (Pip) with ionized phenyl salicylate (PS−), obtained at a constant [Pip] T (= 0.1 M),[PS−] T (= 2× 10− 4 M),[CTABr] T (cetyltrimethylammonium bromide),≤ 0.06 M NaOH,