Organoboron compounds: CDXCV. A regioselective reaction of hydride abstraction in the series of 3-alkyl-3-borabicyclo [4.3. 1] decane ate-complexes

…, SV Baranin, AI Lutsenko, BM Mikhailov

Index: Gurskii, M. E.; Baranin, S. V.; Lutsenko, A. I.; Mikhailov, B. M. Journal of Organometallic Chemistry, 1984 , vol. 270, # 1 p. 17 - 24

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Citation Number: 11

Abstract

Abstract The ate-complexes of 3, 8-dimethyl-, 3, 4, 8-trimethyl-and 3, 4, 4, 8-tetramethyl-3- borabicyclo [4.3. 1] decane react with acetyl chloride to produce the corresponding 2-(3- methylene-5-methylcyclohex-1-yl) alkyl (dimethyl) boranes. The reaction involves the abstraction of a hydride ion from the bridgehead β-carbon atom. The organoboron compounds thus obtained were oxidized with alkaline hydrogen peroxide to the ...