Journal of the American Chemical Society

Bromination of 3-acetocoumarin

CF Koelsch

Index: Koelsch Journal of the American Chemical Society, 1950 , vol. 72, p. 2993

Full Text: HTML

Citation Number: 105

Abstract

1. Summary The reaction of ten bis-(halogenomethyl)-benzenes with hexamethylenetetramine in chloroform solutions is described. Hydrolysis of the salts of m- and p-bis-(chloromethy1)-benzenes according to Sommelet's procedure gave satisfactory yields of m-and pdialdehydes except in the cases where the two nuclear carbons ortho to each chloromethyl group were substituted. These formed basic nitrogen compounds ...