Cerium??Catalyzed α??Hydroxylation Reactions of α??Cyclopropyl β??Dicarbonyl Compounds with Molecular Oxygen

J Christoffers, T Kauf, T Werner…

Index: Christoffers, Jens; Kauf, Thomas; Werner, Thomas; Roessle, Michael European Journal of Organic Chemistry, 2006 , # 11 p. 2601 - 2608

Full Text: HTML

Citation Number: 20

Abstract

Abstract Three α-cyclopropyl β-dicarbonyl compounds have been used as probes for α- radicals as electrophilic reaction intermediates in a cerium-catalyzed α-hydroxylation reaction with molecular oxygen. Since the cyclopropyl group did not ring-open to products ...