Journal of the American Chemical Society

THE RATES OF THE HYDROLYSIS TO BETAINES OF SOME QUATERNARY BASES OF ALPHA-AMINONITRILES. A STUDY OF QUATERNARY AMMONIUM BASES

TD Stewart, K Korpi

Index: Stewart; Korpi Journal of the American Chemical Society, 1932 , vol. 54, p. 3987

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Abstract

The hydrolysis takes place rapidly in dilute alkali, without appreciable side reactions, so a study of the kinetics of the reaction has been undertaken in an attempt to determine, first, the nature of the rate-determining step, and, second, what connection, if any, exists between this reaction and quaternary ammonium base decomposition. Since these are quaternary ammonium compounds it would not have been surprising to find an appreciable ...