Boron atom reactions with the epoxides: vibrational distributions in the product boron oxide (BO)(A2. PI.) state

…, RR Paladugu, J DeHaven, P Davidovits

Index: Bullitt, Marion K.; Paladugu, Rao R.; DeHaven, James; Davidovits, Paul Journal of Physical Chemistry, 1984 , vol. 88, # 20 p. 4542 - 4547

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Citation Number: 3

Abstract

Conclusions The results presented above show that reversible reactions that are first order in eluite concentration cause the elution band to spread. If the relaxation time for the reaction is commensurate with the time for chromatographic retention, the relaxation time can be extracted from the dependence on the chromatographic velocity of the first and second moments of the chromatographic mass distribution of all forms of the eluate at the outlet of ...